Chloramine

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Chloramine
Systematic name Chloroazane
Other names Monochloramine
Chloramide
Molecular formula NH2Cl
Molar mass 51.48 g/mol
CAS number [10599-90-3]
Appearance yellow liquid
Density  ? g/cm3
Solubility (water) Soluble
Melting point -66 °C
Boiling point  ? °C
Related compounds Dichloramine
Nitrogen trichloride
Disclaimer and references

Chloramine (monochloramine) is a toxic substance (NH2Cl) created by the chemical reaction of ammonia and sodium hypochlorite (chlorine bleach) under alkaline conditions. It is a yellow liquid at room temperature. It is commonly used in low concentrations as a disinfectant in municipal water systems as an alternative to chlorination.

Chloramine use by water purification plants is increasing. Chlorine is being phased out in favor of chloramine because chloramine is much more stable and doesn't dissipate from the water before it reaches consumers. There is also less tendency to form halomethanes such as chloroform in the presence of organic materials. Halomethanes have been recognized as a health hazard. Furthermore, water treated with chloramine lacks the distinct chlorine odor of the gaseous treatment and so has improved taste.

Aquarium owners must remove the chloramine from their tap water because it is toxic to fish. Aging the water for a few days removes chlorine but not the more stable chloramine, which can be neutralised using products available at pet stores.

Home brewers use chemicals such as Sodium metabisulfite to remove chloramine from brewing liquor as it cannot be removed by boiling, as is used with chlorine.

Dichloramine (NHCl2) and nitrogen trichloride (NCl3) can be produced by lowering the pH and adjusting the molar ratios of the reactants to favor their formation.

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