Iron(III) oxide

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Iron(III) oxide
Image:Iron(III) oxide.jpg
General
Other names Ferric oxide
Hematite
Molecular formula Fe2O3
Molar mass 159.69 g/mol
Appearance red-brown solid
CAS number [1317-60-8]
Properties
Density and phase 5.24 g/cm3, solid
Solubility in water insoluble
Melting point 1565 °C decomp.
Structure
Coordination
geometry
 ?
Crystal structure  ?
Thermodynamic data
Std enthalpy of
formation
ΔfHo298
−825.50 kJ/mol
Standard molar
entropy
So298
87 J·K−1·mol−1
Hazards
MSDS External MSDS
EU classification  
R-phrases  
S-phrases  
Flash point non-flammable
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions Iron(II) sulfide
Other cations Iron(II) oxide
Iron(II,III) oxide
Ruthenium(IV) oxide
Osmium(IV) oxide
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Iron(III) oxide — also known as ferric oxide, red iron oxide, synthetic maghemite, colcothar, or simply rust — is one of several oxide compounds of iron, and is most notable for its ferromagnetic properties. Its chemical formula is Fe2O3.

The mineral form of ferric oxide is hematite; it is mined as the main ore of iron.

Iron(III) oxide is often used in magnetic storage, for example in the magnetic layer of floppy disks. These consist of a thin sheet of Mylar® plastic, coated with iron(III) oxide. The particles can be magnetised to represent binary data. MICR (Magnetic Ink Character Recognition) also uses iron(III) oxide compounds, suspended in an ink which can be read by special scanning hardware.

The majority of recorded information on earth (such as text and photographs) is stored in the form of magnetization patterns on a thin layer of iron(III) oxide. This is probably because the cost per bit of iron-based magnetic media is currently far less than the cost per bit of any known alternative, such as optical discs, paper books, or microfilm.

A very fine powder of ferric oxide is known as jeweller's rouge, red rouge, or simply rouge. It is used to put the final polish on metallic jewellery and lenses, and historically as a cosmetic.

Rouge cuts slower than some modern polishes, such as cerium(IV) oxide, but is still used in optics fabrication and by jewelers for the superior finish it can produce. When polishing gold, the rouge slightly stains the gold, which contributes to the appearance of the finished piece. Rouge is sold as a powder, paste, or solid bar (with a wax or grease binder). Other polishing compounds are also often called "rouge", even when they do not contain iron oxide.

Uses

Iron(III) Oxide is used in the production of pure iron in a blast furnace. Iron(III) Oxide is also part of an extremly exothermic reaction called a thermite reaction.

Al + Fe2O3Fe + Al2O3

See also

External links



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