Propane

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Propane
Image:Propane.gif
General
Systematic name Propane
Other names Dimethylmethane, LPG,
Propyl Hydride
Molecular formula CH3CH2CH3 or C3H8
SMILES CCC
Molar mass 44.096 g/mol
Appearance Colorless, odorless gas
CAS number [74-98-6]
UN number UN1978
Properties
Density and phase 1.83 g/l, gas
Solubility in water 0.1 g/cm3 (37.8°C)
Melting point -187.6 °C (85.5 K)
Boiling point -42.09 °C (231.1 K)
Structure
Dipole moment 0.083 D
Hazards
MSDS External MSDS
Main hazards Flammable, compressed gas,
frostbite danger
NFPA 704
Image:Nfpa h1.png Image:Nfpa f4.png Image:Nfpa r0.png
Flash point -104 °C
Autoignition temperature 432 °C
R/S statement R: 12
S: 9, 16, 33
RTECS number TX2275000
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Related alkanes ethane, butane
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

A three-carbon alkane, propane is sometimes derived from other petroleum products during oil or natural gas processing.

Contents

Uses

When commonly sold as fuel it is also known as liquified petroleum gas (LPG or LP-gas) and is a mixture of propane with smaller amounts of propylene, butane and butylene, plus ethanethiol as an odorant to allow the normally odorless propane to be smelled.

It is used as fuel in cooking on many barbecues, portable stoves, and in motor vehicles. Propane powers some locomotives, buses, forklifts, and taxis and is used for heat and cooking in recreational vehicles and campers. In many rural areas of the U.S., propane is also used in furnaces, stoves, water heaters, laundry dryers, and other heat-producing appliances. 6.5 million American households use propane as their primary heating fuel.

Local delivery trucks called "bobtails" fill up large tanks that are permanently installed on the property (sometimes called pigs), or other service trucks exchange empty bottles of propane with filled bottles.

Another use of propane is the application as propellant for aerosol sprays, especially after the ban of CFCs. So called "green gas" used in many gas-powered BB or airsoft guns is merely propane as the propellant with 100% silicone oil added to lubricate gaskets. It is also used as a feedstock for the production of base petrochemicals in steam cracking.

U.S. industries using propane include glass makers, brick kilns, poultry farms, and other industries that need portable heat. Additionally, most of the entire U.S. chemical industry uses propane to power their huge facilities that crack or distill industrial chemical products.

Unlike natural gas, propane is heavier than air (1.5 times denser). In its raw state, propane sinks and pools at the floor. Liquid propane will flash to a vapor at atmospheric pressure and appears white due to moisture condensing from the air.

Propane is the fastest growing fuel source in the Third World, especially in China and India. Its use frees up the huge rural populations from time-consuming ancient chores such as wood gathering and allows them more time to pursue other activities, such as increased farming or educational opportunties.

Propane is also being used increasingly more for vehicle fuels. In the U.S., 190,000 on-road vehicles use propane, and 450,000 forklifts use it for power. It is the third most popular vehicle fuel, behind gasoline and diesel. In other parts of the world, propane used in vehicles is known as autogas. About 9 million vehicles worldwide use autogas.

Propane is also instrumental in providing off-the-grid refrigeration, also called gas absorption refrigerators. Made popular by the Servel company, propane-powered refrigerators are highly efficient, do not require electricity, and have no moving parts. Refrigerators built in the 1930s are still in regular use, with little or no maintenance. (However, Servel refrigerators are subject to a 1998 CPSC recall for CO poisoning.) Today, the Unilever company is exploring the use of environmentally friendly propane as a refrigerant.

Source

Propane is not produced for its own sake, but as a byproduct of two other processes: natural gas processing and petroleum refining.

The processing of natural gas involves removal of propane and butane from the natural gas to prevent condensation of these liquids in natural gas pipelines. Additionally, oil refineries produce some propane as a by-product of production of gasoline or heating oil.

The supply of propane cannot be easily adjusted to account for increased demand because of the by-product nature of propane production. About 85% of U.S. propane is domestically produced.

The United States imports about 10-15% of the propane consumed each year. Propane is imported into the United States via pipeline and rail from Canada, and by tankers from Algeria, Saudi Arabia, Venezuela, Norway and the United Kingdom.

After it is produced, American propane is stored in two massive salt caverns located in Mont Belvieu, Texas, and Conway, Kansas. These salt caverns were hollowed out in the 1940s and can store up to 80 million barrels of propane, if not more. The exact storage capacity is not known. When the propane is needed, most of it is shipped by pipelines to other areas of the Midwest, the North, and the South, for use by customers. Propane is also shipped by barge and rail car to selected U.S. areas.

History

Propane was first identified as a volatile component in gasoline by Dr. Walter O. Snelling of the U.S. Bureau of Mines in 1910. Dr. Snelling established the first commercial propane vendor, American Gasol, in 1912.

See also

External links

National Propane Gas Association (U.S.)

UsePropane.com- U.S. industry site

Propane Education and Research Council (U.S.)

Propane Gas Association of Canada

Links to LP-Gas sites around the world

World LP-Gas Association

 
Alkanes

methane
CH4

|
 

ethane
C2H6

|
 

propane
C3H8

|
 

butane
C4H10

|
 

pentane
C5H12

|
 

hexane
C6H14

heptane
C7H16

|
 

octane
C8H18

|
 

nonane
C9H20

|
 

decane
C10H22

|
 

undecane
C11H24

|
 

dodecane
C12H26

 

tridecane
C13H28

|
 

tetradecane
C14H30

|
 

pentadecane
C15H32

|
 

hexadecane
C16H34

|
 

heptadecane
C17H36

|
 

octadecane
C18H38

 

nonadecane
C19H40

|
 

eicosane
C20H42

|
 

heneicosane
C21H44

|
 

docosane
C22H46

|
 

tricosane
C23H48

|
 

tetracosane
C24H50

 

pentacosane
C25H52

|
 

hexacosane
C26H54

|
 

heptacosane
C27H56

|
 

octacosane
C28H58

|
 

nonacosane
C29H60

|
 

triacontane
C30H62

 

hentriacontane
C31H64

|
 

dotriacontane
C32H66

|
 

tritriacontane
C33H68

|
 

tetratriacontane
C34H70

|
 

pentatriacontane
C35H72

|
 

hexatriacontane
C36H74

 



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