Eclipsed
From Freepedia
(Redirected from Torsional strain)
In chemistry an eclipsed conformation is a chemical conformation that exists in any open chain single chemical bond connecting two sp3 hybridised atoms as a conformational energy maximum due to steric hindrance.
In the example of ethane in newman projection it shows that rotation around the carbon-carbon bond is not entirely free but that an energy barrier exists. The ethane molecule in the eclipsed conformation is said to suffer from torsional strain and by a rotation around the carbon carbon bond to the staggered conformation around 12.5 KJ/mole of torsional energy is released.
